Novel graphene oxide/polymer composite membranes for the food industry: structures, mechanisms and recent applications

Crit Rev Food Sci Nutr. 2022;62(14):3705-3722. doi: 10.1080/10408398.2022.2054937. Epub 2022 Mar 29.

Abstract

The membrane can not only be used as food packaging, but also for the separation, fractionation and recovery of food ingredients. Graphene oxide (GO) sheets are a two-dimensional (2 D) material with a unique structure that exhibit excellent mechanical properties, biocompatibility, and flexibility. The corporation of polymer matrix membrane with GO can significantly improve the permeability, selectivity, and antibacterial activity. In this review, the chemical structures of GO, GO membranes and GO/polymer composite membranes are introduced, the permeation mechanisms of molecules through the membranes are discussed and key factors affecting the permeability are presented in detail. In addition, recent applications in the food industry for filtration, bioreactions and active food packaging are analyzed, and limitations and future trends of GO membranes development are also highlighted. GO/polymer composite membranes exhibit excellent permeability, selectivity and strong barrier properties against bacterial and gas permeation. However, current food material filtration and packaging applications of GO/polymer composite membranes are still in the laboratory stage. Future work can focus on the development of large scale uniformly sized GO production, the homogeneous distribution and tight combination of GO in polymer matrixes, the sensing function of GO in packaging, and the verification method of GO toxicology.

Keywords: Active food packaging; graphene oxide; liquid food; membrane fouling; membrane permeability; molecular-sieving.

Publication types

  • Review

MeSH terms

  • Food Packaging
  • Graphite* / chemistry
  • Membranes, Artificial
  • Polymers*

Substances

  • Membranes, Artificial
  • Polymers
  • graphene oxide
  • Graphite