Fluorotelomer alcohols (FTOHs) are important precursors and substitutes of perfluoroalkyl carboxylic acids (PFCAs). This study investigated the long-term trends of FTOHs in a municipal wastewater treatment plant impacted by textile manufacturing industry (T-WWTP) in Wuxi city from 2013 to 2021. For comparison, four domestic wastewater treatment plants (D-WWTPs) were also selected for the investigation. The total concentrations of FTOHs, which were 9.8-43 ng/L, 5.9-29 ng/L and 10-50 ng/g in influent, secondary effluent, and sludge samples from the T-WWTP, were significantly higher than those of the D-WWTPs (p < 0.01). The significant correlation between decrease of mass loads for FTOHs and the increase for PFCAs was observed, suggesting the potential biotransformation of FTOHs to PFCAs. Concentration variation in FTOH concentrations was observed for the T-WWTP, which was in accord with the variation in annual output of textile products in Wuxi city (p = 0.005). The predominance of 8:2 FTOH in the influents of T-WWTP between 2013 and 2016 switched over to 6:2 FTOH in 2020-2021. This work highlighted the textile manufacturing industry as a significant discharge route for FTOHs to municipal WWTP, as well as the dramatic change in the usage of FTOHs in the textile manufacturing industry in Wuxi.
Keywords: Industrial wastewater; Municipal wastewater treatment plant; Per- and polyfluoroalkyl substances; Precursor; Substitute.
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