Facile fabrication of highly dispersed Pd catalyst on nanoporous chitosan and its application in environmental catalysis

Abstract

With the development of society, the problem of environmental pollution is becoming increasingly serious, such as the typical pollution of nitro compounds or dyes in wastewater. An effective strategy to remove these organic pollutants is catalytic conversion, including converting them into more chemically valuable compounds. Herein, a nanoporous chitosan microsphere derived from seafood waste resources of chitin was constructed via sol-gel method, which was used as supports to successfully fabricate a highly dispersed Pd nano-catalyst (mean diameter ~ 1.8 nm) via a facile way based on its interconnected nanoporous structure and rich functional -OH/-NH₂ groups. The synthetic catalyst was applied to the hydrogenation of toxic nitro compounds, which could efficiently and selectively catalyze the conversion of nitro compounds. The catalyst was also used for the degradation of some representative dyes, which also showed good activity and stability, suggesting potential of applications in green environmental governance.

Keywords: Chitosan; Environment catalysis; Palladium; Renewable resource; Supported catalyst.