Advances in Material Nanosensitization: Refractive Property Changes as the Main Parameter to Indicate Organic Material Physical-Chemical Feature Improvements

Materials (Basel). 2022 Mar 15;15(6):2153. doi: 10.3390/ma15062153.

Abstract

In the current paper, the results of the sensitization process' influence on the refractive organic materials' features are shown. The correlation between the refractive properties and the intermolecular charge transfer effect of doped organic thin films are shown via estimation of the laser-induced change in the refractive index. The refractive parameter is shown for a model organics matrix based on a polyimide doped with fullerenes, carbon nanotubes, reduced graphene oxides, etc. A second harmonic of the Nd-laser was used to record the holographic gratings in the Raman-Nath diffraction conditions at different spatial frequencies. The laser-induced refractive index change was considered to be an indicator in order to estimate the basic organic materials' physical-chemical characteristics. Additional data are presented for the liquid crystal cells doped with nanoparticles. The correlation between the content of the nanoobjects in the organics' bodies and the contact angle at the thin film surfaces is shown. Some propose to use this effect for general optoelectronics, for the optical limiting process, and for display application.

Keywords: carbon nanotubes; fullerenes; functional nanomaterials; liquid crystal; organics; polyimide; reduced graphene oxides; refractive index change; sensitization; surfaces.

Publication types

  • Review