Additive is a conventional way to enhance halide perovskite active layer performance in multiaspects. Among them, π-conjugated molecules have significantly special influence on halide perovskite due to the superior electrical conductivity, rigidity property, and good planarity of π-electrons. In particular, π-conjugated additives usually have stronger interaction with halide perovskites. Therefore, they help with higher charge mobility and longer device lifetime compared with alkyl-based molecules. In this review, the detailed effect of conjugated molecules is discussed in the following parts: defect passivation, lattice orientation guidance, crystallization assistance, energy level rearrangement, and stability improvement. Meanwhile, the roles of conjugated ligands played in low-dimensional perovskite devices are summarized. This review gives an in-depth discussion about how conjugated molecules interact with halide perovskites, which may help understand the improved performance mechanism of perovskite device with π-conjugated additives. It is expected that π-conjugated organic additives for halide perovskites can provide unprecedented opportunities for the future improvement of perovskite devices.
Keywords: additives; halide perovskites; light-emitting diodes; solar cells; π-conjugation.
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