A 10-year-long measurement of water-soluble inorganic ions in PM2.5 was made in Beijing from June 2011 to December 2020, to investigate the interannual trends of chemical characteristics of PM2.5 and to provide insights into the future prevention and control of PM2.5 pollution. From 2011 to 2020, with the implementation of strict air pollution control strategies, significant changes of PM2.5 have been observed in Beijing, with NO3-, SO42- and NH4+ decreasing at rates of 5.10, 8.80 and 7.64% yr-1 respectively. The percentages of NO3- and SO42- under elevated pollution levels were investigated. When PM2.5 values fell in the range of 0-400 μg m-3, NO3-/ SO42- values were mostly higher than 1 and showed upward trends from 2011 to 2020. However, under extremely heavy haze conditions, SO42- dominated PM2.5 formation. This result was closely related to the change characteristics of the oxidation ratio of sulfate (SOR), the oxidation ratio of nitrate (NOR) and gaseous precursors under different pollution levels. The change characteristics of NOR and SOR under elevated PM2.5 levels indicated that the aqueous phase oxidation was the key process driving SO42- formation; while as for NO3-, in addition to the availability of NH4+, the atmospheric oxidation capacity made crucial roles. The analysis of typical haze episodes during the past decade indicated that the emission reduction of gaseous pollutants, especially SO2, made great contributions to the improved PM2.5 air quality in Beijing. We highlighted that future efforts should focus on enhanced reduction of NO2 emission and control of atmospheric oxidation capacity to further reduce particulate nitrate formation.
Keywords: Long-term observation; NOR; SOR; Secondary inorganic component.
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