Recent Approaches in the Catalytic Transformation of Biomass-Derived 5-Hydroxymethylfurfural into 2,5-Diformylfuran

ChemSusChem. 2022 Jul 7;15(13):e202200220. doi: 10.1002/cssc.202200220. Epub 2022 Apr 22.

Abstract

The conversion of biomass into a great variety of valuable chemicals, polymers, and fuels gives a sustainable alternative for the insufficiency of non-renewable fossil fuel resources and reduces environmental pollution. 5-Hydroxymethylfurfural (HMF), converted from sustainable carbohydrates, is a significant building block chemical, and the selective oxidation of HMF into 2,5-diformylfuran (DFF) presents an ongoing challenge. DFF is a versatile platform molecule derived from biomass and has promising application in pharmaceuticals and polymers. This Review provides an overview of the latest developments of efficient catalytic systems for the sustainable conversion of HMF to DFF.

Keywords: 2,5-diformylfuran; 5-hydroxymethylfurfural; biomass conversion; catalysis; selective oxidation.

Publication types

  • Review

MeSH terms

  • Biomass
  • Furaldehyde* / analogs & derivatives
  • Furaldehyde* / chemistry
  • Furans
  • Polymers*

Substances

  • Furans
  • Polymers
  • 5-hydroxymethylfurfural
  • Furaldehyde
  • 2,5-diformylfuran