The Decisive Role of Spin States and Spin Coupling in Dictating Selective O2 Adsorption in Chromium(II) Metal-Organic Frameworks

Reshma Jose; Srinivasu Kancharlapalli; Tapan K Ghanty; Sourav Pal; Gopalan Rajaraman

doi:10.1002/chem.202200661

The Decisive Role of Spin States and Spin Coupling in Dictating Selective O₂ Adsorption in Chromium(II) Metal-Organic Frameworks

Chemistry. 2022 Mar 28;28(18):e202200661. doi: 10.1002/chem.202200661. Epub 2022 Mar 11.

Authors

Reshma Jose¹, Srinivasu Kancharlapalli², Tapan K Ghanty^{2

3}, Sourav Pal⁴, Gopalan Rajaraman¹

Affiliations

¹ Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, 400076, India.
² Theoretical Chemistry Section, Bhabha Atomic Research Centre, Mumbai, 400085, India.
³ Present address: Bio-Science Group, Bhabha Atomic Research Centre, Mumbai, 400085, India.
⁴ Department of Chemistry, Indian Institute of Science Education and Research, Kolkata, Mohanpur, Nadia, 741246, India.

PMID: 35277904
DOI: 10.1002/chem.202200661

Abstract

Invited for the cover of this issue are Sourav Pal, Gopalan Rajaraman and co-workers at the Indian Institute of Technology Bombay, the Bhabha Atomic Research Centre and the Indian Institute of Science Education and Research. The image depicts how a mixture of atmospheric gases such as CO₂ , H₂ , N₂ and O₂ can be selectively separated using a Cr metal-organic framework where spin state and spin coupling play a crucial role. Read the full text of the article at 10.1002/chem.202104526.