Submicron particle formation from co-firing of coal and municipal sewage sludge

Ao Zhou; Wenjing Ma; Renhui Ruan; Shilin Yu; Houzhang Tan; Shuanghui Deng; Kun Liang; Kai Liu; Donglin Han; Xuebin Wang

doi:10.1016/j.jenvman.2022.114863

Submicron particle formation from co-firing of coal and municipal sewage sludge

J Environ Manage. 2022 Mar 8:311:114863. doi: 10.1016/j.jenvman.2022.114863. Online ahead of print.

Authors

Ao Zhou¹, Wenjing Ma¹, Renhui Ruan², Shilin Yu¹, Houzhang Tan¹, Shuanghui Deng¹, Kun Liang³, Kai Liu³, Donglin Han⁴, Xuebin Wang⁵

Affiliations

¹ MOE Key Laboratory of Thermo-Fluid Science and Engineering, Xi'an Jiaotong University, Xi'an, 710049, China.
² MOE Key Laboratory of Thermo-Fluid Science and Engineering, Xi'an Jiaotong University, Xi'an, 710049, China. Electronic address: renhuiruan@mail.xjtu.edu.cn.
³ China Tobacco Sichuan Industrial Co., Ltd., ChengLong Avenue #56, Jinjiang District, Chengdu, 610066, China.
⁴ China Tobacco Sichuan Industrial Co., Ltd., ChengLong Avenue #56, Jinjiang District, Chengdu, 610066, China. Electronic address: 76133686@qq.com.
⁵ MOE Key Laboratory of Thermo-Fluid Science and Engineering, Xi'an Jiaotong University, Xi'an, 710049, China. Electronic address: wxb005@mail.xjtu.edu.cn.

PMID: 35276565
DOI: 10.1016/j.jenvman.2022.114863

Abstract

With the increasing production of municipal sewage sludge (MSS) in China every year, the co-firing of MSS and pulverized coal is getting more and more widely applied in large coal-fired power plants. The co-firing of MSS and pulverized coal will produce a large amount of particulate matter (PM) emissions, especially submicron particles. In this paper, the formation characteristics of submicron particles in the co-firing process of coal and MSS were studied in a drop tube furnace. The influence of the furnace temperature and the addition ratio of sludge on the particle size distribution and element composition of submicron particles in MSS, pulverized coal combustion and co-firing was mainly studied. The experimental results show that the furnace temperature has an influence on the formation of PM_0.4. For sludge combustion, increasing the furnace temperature will promote the formation of PM_0.4. The main reason is that increasing the furnace temperature promotes the gasification of Si, S, Fe, and P to form the precursor of PM_0.4 or PM_0.4. At same furnace temperature, the volume concentration and mass concentration of PM_0.4 produced from pulverized coal combustion are less than that of sludge. Different from sludge combustion, co-firing of pulverized coal and sludge has a synergistic effect on eliminating PM_0.4 formation. Increasing the addition ratio of sludge can decrease the volume concentration and mass concentration of PM_0.4. This is because that aluminosilicates formed during co-firing promotes the scavenge Si, Ca, Fe, thereby reducing the precursors of PM_0.4 and the mass yield of PM_0.4. Increasing the furnace temperature in co-firing can inhibit the formation of PM_0.4. When the furnace temperature is between 1100 °C and 1300 °C, increasing the furnace temperature will reduce the Fe content and increase the content of Si, Ca, Na, K, and P in PM_0.4. However, the reduction of Fe and the increase of Si, Ca, Na, K, and P in PM_0.4 offset each other, resulting in an insensitive relationship between the mass yield of PM_0.4 and the furnace temperature.

Keywords: Co-firing; Coal-fired power plant; Municipal sewage sludge; PM(0.4).