Facile Fabrication of Polyaniline/Pbs Nanocomposite for High-Performance Supercapacitor Application

Ahmed Gamal; Mohamed Shaban; Mohammad BinSabt; Mahmoud Moussa; Ashour M Ahmed; Mohamed Rabia; Hany Hamdy

doi:10.3390/nano12050817

Facile Fabrication of Polyaniline/Pbs Nanocomposite for High-Performance Supercapacitor Application

Nanomaterials (Basel). 2022 Feb 28;12(5):817. doi: 10.3390/nano12050817.

Authors

Ahmed Gamal¹, Mohamed Shaban^{1

2}, Mohammad BinSabt³, Mahmoud Moussa^{4

5}, Ashour M Ahmed¹, Mohamed Rabia^{1

5}, Hany Hamdy¹

Affiliations

¹ Nanophotonics and Applications Laboratory, Physics Department, Faculty of Science, Beni-Suef University, Beni-Suef 62514, Egypt.
² Department of Physics, Faculty of Science, Islamic University of Madinah, P.O. Box 170, Al-Madinah Almonawara 42351, Saudi Arabia.
³ Chemistry Department, Faculty of Science, Kuwait University, P.O. Box 5969, Safat 13060, Kuwait.
⁴ Future Industries Institute, University of South Australia, Mawson Lakes, SA 5095, Australia.
⁵ Chemistry Department, Faculty of Science, Beni-Suef University, Beni-Suef 62511, Egypt.

Abstract

In this work, a polyaniline/lead sulfide (PANI/PbS) nanocomposite was prepared by combining the in situ oxidation polymerization method and the surface adsorption process. This nanocomposite was applied as a supercapacitor electrode. The crystal structure, nanomorphology, and optical analysis of PANI and PANI/PbS were investigated. The electrochemical performance of the designed PANI/PbS electrode-based supercapacitor was tested by using cyclic voltammetry (CV), chronopotentiometry (CP), and AC impedance techniques in HCl and Na₂SO₄ electrolytes. The average crystallite size of the PANI/PbS nanocomposite is about 43 nm. PANI/PbS possesses an agglomerated network related to PANI with additional spherical shapes from PbS nanoparticles. After the PANI/PbS nanocomposite formation, there are enhancements in their absorption intensities. At a current density of 0.4 A g^-1, the specific capacitance of PANI/PbS in Na₂SO₄ and HCl was found to be 303 and 625 F g^-1, respectively. In HCl (625 F g^-1 and 1500 mF cm^-2), the gravimetric and areal capacitances of the PANI/PbS electrode are nearly double those of the Na₂SO₄ electrolyte. Also, the average specific energy and specific power density values for the PANI/PbS electrode in HCl are 4.168 Wh kg^-1 and 196.03 W kg^-1, respectively. After 5000 cycles, the capacitance loses only 4.5% of its initial value. The results refer to the high stability and good performance of the designed PANI/PbS as a supercapacitor electrode.

Keywords: PANI/PbS nanocomposite; capacitance; electrochemical properties; stability; supercapacitor.