Acid rain is mainly composed of sulfuric acid and nitric acid aqueous solutions, which can deteriorate the mechanical properties of soil and thus threaten the safety of soil engineerings. In this paper, the influence of sulfuric acid rain on mechanical properties of loess soil samples was studied. The diluted sulfuric acid solution has respectively pH 5.0, 4.0 and 3.0 to simulate the acid rain condition, and the triaxial compressional tests and scanning electron microscope were carried out to investigate the deteriorated properties and evolution of the microstructure of the saturated loess samples. The results demonstrated that acid rain made the porosity of loess samples larger, and changed the pore distribution and contacts of soil grains, so that the mechanical properties of loess samples varied in some degree. With the decrease of pH value, both the peak value of the deviatoric stress and volumetric contraction of loess samples decreased, which reduced the parameters of shear strength of loess samples. Furthermore, a framework of the chemical-mechanical model for loess under the action of acid rain was established, in which loess was considered as a porous medium material, and the influences of acid rain with different pH values were taken into account in the double-hardening constitutive model, and the model was also verified by the triaxial test results finally.
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