Synergy between plasmonic and sites on gold nanoparticle-modified bismuth-rich bismuth oxybromide nanotubes for the efficient photocatalytic CC coupling synthesis of ethane

Abstract

The photocatalytic reduction of carbon dioxide (CO₂) to fossil fuels has attracted widespread attention. However, obtaining the high value-added hydrocarbons, especially C₂₊ products, remains a considerable challenge. Herein, gold (Au) nanoparticle-modified bismuth-rich bismuth oxybromide Bi₁₂O₁₇Br₂ nanotube composites were designed and tested. Au nanoparticles act as electron traps and thermal electron donors that promote the efficient separation and migration of carriers to form the C₂₊ product. As a result, compared with the pure Bi₁₂O₁₇Br₂ nanotubes, Au@Bi₁₂O₁₇Br₂ composites can not only produce the carbon monoxide (CO) and methane (CH₄), but also covert CO₂ into ethane (C₂H₆). In this study, Au@Bi₁₂O₁₇Br₂-700 was used to obtain a C₂H₆ production rate of 29.26 μmol h^-1 g^-1. The selectivities during a 5-hour test reached 94.86% for hydrocarbons and 90.81% for C₂H₆. The proposed approach could be used to design high-performance photocatalysts to convert CO₂ into high value-added hydrocarbon products.

Keywords: Au; Bi(12)O(17)Br(2) nanotubes; Ethane; Photocatalytic CO(2) reduction; Product selectivity.