Removal of methyl orange using combined ZnO/Fe2O3/ZnO-Zn composite coated to the aluminium foil in the presence of simulated solar radiation

Nemanja D Banić; Jugoslav B Krstić; Maria M Uzelac

doi:10.1007/s11356-022-19374-w

Removal of methyl orange using combined ZnO/Fe₂O₃/ZnO-Zn composite coated to the aluminium foil in the presence of simulated solar radiation

Environ Sci Pollut Res Int. 2022 Jul;29(34):51521-51536. doi: 10.1007/s11356-022-19374-w. Epub 2022 Mar 4.

Authors

Nemanja D Banić¹, Jugoslav B Krstić², Maria M Uzelac³

Affiliations

¹ Faculty of Sciences, Department of Chemistry, Biochemistry and Environmental Protection, University of Novi Sad, Trg D. Obradovića 3, 21000, Novi Sad, Serbia. nemanja.banic@dh.uns.ac.rs.
² Institute of Chemistry, Technology and Metallurgy, Department of Catalysis and Chemical Engineering, University of Belgrade, Njegoševa 12, 11000, Belgrade, Serbia.
³ Faculty of Sciences, Department of Chemistry, Biochemistry and Environmental Protection, University of Novi Sad, Trg D. Obradovića 3, 21000, Novi Sad, Serbia.

PMID: 35244843
DOI: 10.1007/s11356-022-19374-w

Abstract

In this paper, the optimal preparative conditions (current density, deposition temperature, calcination temperature) for the original electrochemical synthesis of ZnO-Zn coating on aluminum foil support (ZnAF) were examined and determined the application for the removal of methyl orange (MO). Optimal application conditions for removing MO (volume and concentration of a treated solution) were also determined. In the following, four immobilized ZnO/Fe₂O₃ photocatalysts with different molar ratios of Zn to Fe (0.42, 0.84, 1.68, and 3.36) were synthesized via the chemical precipitation method on optimized electrochemically synthesized ZnAF support. Characterization studies of synthesized materials included SEM-EDS and Raman scattering analyses. The efficiency of these catalysts for MO removal in the presence/absence of simulated solar radiation (SSR) was investigated. The adsorption isotherms were investigated, and the results show that the adsorption data were best fitted with the Freundlich adsorption isotherm model. Assessment of the thermodynamic parameters showed that although the adsorption process was weakly endothermic over the range of temperatures studied, the relatively high entropy change gave an overall negative change in Gibbs free energy making the processes spontaneous. In the presence of SSR, the optimal molar ratio of Zn to Fe was determined to be 1.68. The possibility of potential reusing the catalyst was examined six times in a row. The possibility for multiple uses of suspension, which is used for immobilization, was also examined. It was also determined that the application of the 1.68Zn/Fe/ZnAF/H₂O₂/SSR system after the dye removal generates hydrogen at a rate of 186.5 μmol g^-1 after 6 h. Furthermore, in the presence of SSR and using a suspended form of catalyst, the removal efficiency was 1.6 times higher than the efficiency achieved with immobilized ZnO/Fe₂O₃ catalyst. Using the HPLC method for 1.68Zn/Fe/ZnAF/SSR system, five primary intermediates were found to be formed. The applicability of ZnO/Fe₂O₃/ZnAF for removal of other dyes was also examined.

Keywords: Adsorption; Electrolysis; Immobilized catalyst; Methyl orange; Photodegradation; ZnO/Fe2O3.

MeSH terms

Adsorption
Aluminum
Azo Compounds
Coloring Agents / chemistry
Hydrogen Peroxide
Zinc Isotopes
Zinc Oxide* / chemistry

Substances

Azo Compounds
Coloring Agents
Zinc Isotopes
Zinc-68
methyl orange
Hydrogen Peroxide
Aluminum
Zinc Oxide