Lotus-like Ni@NiO nanoparticles embedded porous carbon derived from MOF-74/cellulose nanocrystal hybrids as solid phase microextraction coating for ultrasensitive determination of chlorobenzenes from water

Shengrui Xu; Panlong Dong; Hailin Liu; Huimin Li; Changpo Chen; Suling Feng; Jing Fan

doi:10.1016/j.jhazmat.2022.128384

Lotus-like Ni@NiO nanoparticles embedded porous carbon derived from MOF-74/cellulose nanocrystal hybrids as solid phase microextraction coating for ultrasensitive determination of chlorobenzenes from water

J Hazard Mater. 2022 May 5:429:128384. doi: 10.1016/j.jhazmat.2022.128384. Epub 2022 Feb 1.

Authors

Shengrui Xu¹, Panlong Dong², Hailin Liu², Huimin Li², Changpo Chen², Suling Feng³, Jing Fan⁴

Affiliations

¹ Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, PR China; Henan Key Laboratory for Environmental Pollution Control, Key Laboratory for Yellow River and Huai River Water Environmental Pollution and Control, Ministry of Education, School of Environment, Henan Normal University, Xinxiang 453007, PR China. Electronic address: xushengrui@126.com.
² Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, PR China.
³ Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, PR China. Electronic address: slfeng@htu.cn.
⁴ Henan Key Laboratory for Environmental Pollution Control, Key Laboratory for Yellow River and Huai River Water Environmental Pollution and Control, Ministry of Education, School of Environment, Henan Normal University, Xinxiang 453007, PR China.

PMID: 35236041
DOI: 10.1016/j.jhazmat.2022.128384

Abstract

Lotus-like Ni@NiO embedded porous carbons (Ni@NiO/PCs) were fabricated by pyrolysis of MOF-74/cellulose nanocrystal hybrids, and used as a solid phase microextraction (SPME) coating for ultrasensitive determination of chlorobenzenes (CBs) from water combined with gas chromatography-mass spectrometry. Owing to its abundant chemical groups, high porosity, and excellent thermal stability, the as-prepared Ni@NiO/PCs presented superior extraction performance compared to commercial SPME coatings. Notably, Ni@NiO/PCs derived from MOF-74/CNC hybrids presented higher extraction efficiencies towards CBs than that derived from pristine CNC and MOF-74 due to the formation of micro/mesopores and more abundant oxygen-containing groups. Under the optimum extraction conditions, the proposed analytical method presented wide linearity range (0.5-1500 ng L^-1), ultra-low detection of limit (0.005-0.049 ng L^-1), and excellent precision with relative standard deviations of 4.7-9.2% for a single fiber and 8.8-10.9% for 5 fibers, and long lifetime (≥160 times). The proposed analytical method was finally applied for determination of CBs from real water samples, and the recoveries were in the range of 93.2-116.8% towards eight CBs. This study delivered a novel and efficient sorbent as SPME coating to extraction and determination of CBs from water.

Keywords: Cellulose nanocrystal; Chlorobenzenes; Metal-organic frameworks; Porous carbon; Solid phase microextraction.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Carbon
Cellulose
Chlorobenzenes
Lotus*
Nanoparticles* / analysis
Porosity
Solid Phase Microextraction / methods
Water / chemistry
Water Pollutants, Chemical* / analysis

Substances

Chlorobenzenes
Water Pollutants, Chemical
Water
Carbon
Cellulose