The formation of volumetric nanogratings in fused silica by femtosecond laser pulses are shown to afford new opportunities for manipulating the physical shape and tailoring the optical properties of the modification zone by harnessing unconventional beam shapes. The nanograting assembly was observed to rigorously follow the beam elongation effects induced with conical-shaped phase fronts, permitting a scaling up of the writing volume. Detailed optical characterization of birefringence, dichroism, and scattering loss pointed to flexible new ways to tune the macroscopic optical properties, with advantages in decoupling the induced phase retardation from the modification thickness by controlling the conical phase front angle. Further insights into an unexpected asymmetric response from Gaussian beams modified with concave and convex phase fronts have been provided by nonlinear propagation simulations of the shaped-laser light.