Catalytic dehydrogenation coupling of methane (DCM) represents an effective way to convert natural gas to more useful C2 products (C2H6, C2H4). In this work, BaCe0.85Tb0.05Co0.1O3-δ (BCTCo) perovskite hollow fiber membranes were fabricated by the combined phase inversion and sintering method. SrCe0.95Yb0.05O3-δ (SCYb) perovskite oxide was loaded as a catalyst onto the inner hollow fiber membrane surface, which promoted the CH4 conversion and the C2 hydrocarbon selectivity during the DCM reaction. The introduction of steam into the methane feed gas mixture elevated the C2 selectivity and yield due to the alleviation of coke deposition. Switching N2 to air as the sweep gas further increased the C2 selectivity and yield. However, the conversion of methane was limited by both the low permeability of the membrane and the insufficient catalytic activity of the catalyst, leading to low C2 yield.
Keywords: catalyst loading; dehydrogenation coupling of methane (DCM); hollow fiber; perovskite membrane; proton conductor.