Nanocomposite membrane (NCM) is deemed as a practical and green separation solution which has found application in various fields, due to its potential to delivery excellent separation performance economically. NCM is enabled by nanofiller, which comes in a wide range of geometries and chemical features. Despite numerous advantages offered by nanofiller incorporation, fabrication of NCM often met processing issues arising from incompatibility between inorganic nanofiller and polymeric membrane. Contemporary, functionalization of nanofiller which modify the surface properties of inorganic material using chemical agents is a viable approach and vigorously pursued to refine NCM processing and improve the odds of obtaining a defect-free high-performance membrane. This review highlights the recent progress on nanofiller functionalization employed in the fabrication of gas-separative NCMs. Apart from the different approaches used to obtain functionalized nanofiller (FN) with good dispersion in solvent and polymer matrix, this review discusses the implication of functionalization in altering the structure and chemical properties of nanofiller which favor interaction with specific gas species. These changes eventually led to the enhancement in the gas separation efficiency of NCMs. The most frequently used chemical agents are identified for each type of gas. Finally, the future perspective of gas-separative NCMs are highlighted.
Keywords: functionalization; gas separation; membrane; nanocomposite; nanomaterial.