Metalloligand-based coordination polymer embedding the nitrosyl ruthenium complex for photoactive materials with bound nitric oxide

Vasily Vorobyev; Anastasia M Cheplakova; Elena D Stolyarova; Vladislav Yu Komarov; Gennadiy A Kostin

doi:10.1039/d1dt03943a

Metalloligand-based coordination polymer embedding the nitrosyl ruthenium complex for photoactive materials with bound nitric oxide

Dalton Trans. 2022 Mar 8;51(10):3954-3963. doi: 10.1039/d1dt03943a.

Authors

Vasily Vorobyev¹, Anastasia M Cheplakova¹, Elena D Stolyarova¹, Vladislav Yu Komarov¹, Gennadiy A Kostin¹

Affiliation

¹ Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Science, Novosibirsk 630090, Russia. vasily.vorob@gmail.com.

PMID: 35171165
DOI: 10.1039/d1dt03943a

Abstract

The stability of a photoactivated isonitrosyl state was boosted by confining a pre-designed bicarboxylate ligand with a ruthenium nitrosyl fragment in a 2D metal-organic framework. The novel Zn/Ru-based MOF, {Zn[RuNO(H₂O)(inic)₂(OH)₂]₂}·12H₂O (inic = isonicotinate), was obtained with enhanced isonitrosyl stability by 30 K (up to 200 K) compared to the related ruthenium-only complex.