The production technology of mineral soda alumina glass: A perspective from microstructural analysis of glass beads in Iron Age Taiwan

PLoS One. 2022 Feb 15;17(2):e0263986. doi: 10.1371/journal.pone.0263986. eCollection 2022.

Abstract

Mineral soda alumina (m-Na-Al) glass is a common glass production group found around the Indo-Pacific region. In Iron Age Taiwan, its presence dates back to the early 1st millennium AD. This research discusses m-Na-Al glass beads excavated from Iron Age sites in Taiwan. No production sites for m-Na-Al have been found, but microstructural analysis suggests m-Na-Al glass appears to originate around South Asia and is exchanged widely. SEM-EDS and EPMA were used to analyse red, orange, yellow, green and blue m-Na-Al glass. The microstructure of the glass shows the presence of plagioclase and alkali feldspar relics in the glass, suggesting a low manufacturing temperature. Copper-based colourants are identified in red, orange, blue and green glass, while lead tin oxide is used in yellow and green glass. It appears that various types of copper-containing raw materials were procured by craftspeople, and a self-reduction process for producing red and orange glass is tentatively proposed. Additionally, the microstructure of yellow glass reveals different colouring paths were used. These results increase our understanding of the selection of raw materials, and provide an impetus for further research on the cross craft interaction between glass and copper production.

MeSH terms

  • Aluminum Oxide / chemistry*
  • Archaeology
  • Color
  • Glass / analysis*
  • Microspheres
  • Sodium / chemistry*
  • Taiwan

Substances

  • Sodium
  • Aluminum Oxide

Grants and funding

The author(s) received no specific funding for this work.