Facile fabrication of surface vulcanized Co-Fe spinel oxide nanoparticles toward efficient 4-nitrophenol destruction

Abstract

Developing efficient modulation strategies to boost the degradation efficiencies of non-noble metal catalysts for toxic phenolic compounds involving peroxymonosulfate (PMS)-based oxidation processes is essential but remains an arduous challenge. This study reports the one-pot construction of in-situ surface vulcanized CoFe₂O₄ @carbon (S_x-CF@C) to boost the PMS activation for 4-nitrophenol (4-NP) destruction. The direct pyrolysis of an aerogel precursor consisted of cobalt nitrate, ferric nitrate, melamine, and thiourea enables the as-formed S_x-CF@C with hierarchical structure, rich oxygen vacancies, and electron/mass transfer, thereby considerably promoting PMS activation performance of S_x-CF@C toward 4-NP degradation. Specifically, the optimal S_0.2-CF@C can achieve a removal efficiency of 99% for 4-NP destruction (20 mg/L) through PMS activation. Meanwhile, the catalyst also has generality to degrade a variety of antibiotic and dye organic pollutants. The radical quenching and electron paramagnetic resonance tests reveal the radical and non-radical activation mechanism in the S_0.2-CF@C/PMS system. The degradation pathway for 4-NP destruction over the S_0.2-CF@C/PMS system is proposed. This study provides an efficient approach to modulate the PMS activation performance of ferrite spinel materials toward the degradation of acute phenolic compounds.

Keywords: 4-nitrophenol removal; Oxygen vacancies; Peroxymonosulfate activation; Radical/non-radical pathway; Sulfur-doped CoFe(2)O(4).