Radioactive and stable isotopes reveal variations in nearshore submarine groundwater discharge composition and magnitude across low inflow northwestern Gulf of Mexico estuaries

Abstract

To determine how submarine groundwater discharge (SGD) magnitudes and composition (fresh or saline/recirculated) vary in nearshore low inflow estuaries across ⁓125 km of a semiarid coastline, this study assessed three south Texas estuaries, using radon [²²²Rn], radium [²²⁶Ra and ²²⁴Ra], and water isotopes [δ¹⁸O and δD]. Mass balance models of time-series ²²²Rn, found to be representative of total SGD in this study, revealed much higher SGD inputs to the Nueces Estuary (average [x̅] Nueces, Corpus Christi and Oso Bays: 120, 83, and 44 cm·d^-1, respectively), attributed to anthropogenically-disturbed substrates and potentially surfacing growth-faults. The lowest ²²²Rn-derived SGD occurred in the Upper Laguna Madre Estuary (x̅: Upper Laguna Madre and Baffin Bay: 21 and 18 cm·d^-1, respectively), explained by the drier climate, lower anthropogenic disturbance, and neighboring groundwater cone of depression. Aransas Bay in the Mission Aransas Estuary received greater average annual precipitation but exhibited low total SGD rates (x̅: 23 cm·d^-1). Seasonally, average ²²²Rn-derived SGD rates increased following Hurricane Harvey (43 cm·d^-1 in spring to 64 cm·d^-1 in summer). In the Nueces Estuary, the overall ²²²Rn-derived SGDs were substantially higher than SGDs from ²²⁴Ra and ²²⁶Ra. The closer agreement between ²²⁴Ra and ²²²Rn-derived SGD and larger ²²⁴Ra rates in the Upper Laguna Madre Estuary, Aransas Bay and Oso Bay indicate that saline/recirculated SGD contributions were significant. Values of δ¹⁸O and δD confirm these types of inputs, with effects of evaporation/salinization more pronounced where recirculation was predominant and the opposite where terrestrial/²²²Rn-derived SGD inputs dominate. ²²⁶Ra-derived SGDs were lower than the ²²⁴Ra due to different behavior of the two isotopes while released into water following transport through saline and fine-grained estuarine sediments or due to wind-driven disturbances.

Keywords: Mission-Aransas Estuary; Nueces Estuary; Radon and radium; Stable isotopes; Submarine groundwater discharge; Texas coast; Upper Laguna Madre.