A ternary strategy of halogen-free solvent processing can open up a promising pathway for the preparation of polymer solar cells (PSCs) on a large scale and can effectively improve the power conversion efficiency with an appropriate third component. Herein, the green solvent o-xylene (o-XY) is used as the main solvent, and the non-fullerene acceptor Y6-DT-4F as the third component is introduced into the PBB-F:IT-4F binary system to broaden the spectral absorption and optimize the morphology to achieve efficient PSCs. The third component, Y6-DT-4F, is compatible with IT-4F and can form an "alloy acceptor", which can synergistically optimize the photon capture, carrier transport, and collection capabilities of the ternary device. Meanwhile, Y6-DT-4F has strong crystallinity, so when introduced into the binary system as the third component can enhance the crystallization, which is conducive to the charge transport. Consequently, the optimal ternary system based on PBB-F:IT-4F:Y6-DT-4F achieved an efficiency of 15.24%, which is higher than that of the binary device based on PBB-F:IT-4F (13.39%).
Keywords: alloy; charge transport; halogen-free solvent; polymer solar cells; third component.