Multiple stable isotopes and geochemical approaches to elucidate groundwater salinity and contamination in the critical coastal zone: A case from the Bou-areg and Gareb aquifers (North-Eastern Morocco)

Abstract

Mediterranean areas are characterized by complex hydrogeological systems, where water resources are faced with several issues such as salinity and pollution. Fifty-one water samples were gathered from the Bou-areg coastal and the Gareb aquifers to evaluate the source of water salinity and to reveal the processes of the different sources of pollution using a variety of chemical and isotopic indicators (δ²H-H2O, δ¹⁸O-H2O, δ³⁴S-SO4, and δ¹⁸O-SO4). The results of the hydrochemical analysis of water samples show that the order of dominated elements is Cl^- > HCO₃^- > SO4₂^- > NO₃^- and Na⁺ > Ca²⁺ > Mg²⁺ > K⁺ and evidenced extremely high salinity levels (EC up to 22000 μS/cm). All samples exceeded the WHO drinking water guidelines, making them unfit for human consumption. Ion ratio diagrams, isotopic results, and graphical comparing indicate that the mineralization of groundwater in the area, is controlled by carbonate dissolution, evaporite dissolution, ion exchange, and sewage invasion. The return of irrigation water plays a significant role as well in the groundwater recharge and its mineralization by fertilizers mainly. Evaporites (Gypsum), sewage, and fertilizers constitute the main sources of sulfates in the investigated water resources. These scientific results will be an added value for decision-makers to more improve the sustainable management of groundwater in water-stressed regions. The use of chemical and isotopic tracers once again shows their relevance in such zones where systematic monitoring is lacking.

Keywords: Coastal aquifer; Groundwater salinization; Ionic ratios; Stable isotopes; Sulfate.