Efficient remediation of chlorpyrifos pesticide from contaminated water by superparamagnetic adsorbent based on Arabic gum-grafted-polyamidoxime

Abstract

A novel organic/inorganic biosorbent hydrogel nanocomposite based on Arabic Gum-grafted-polyamidoxime and CuFe₂O₄ magnetic nanoparticles (AG-g-PAO/CuFe₂O₄) was prepared in three steps. The prepared hydrogel nanocomposite was well characterized using Fourier transform infrared (FT-IR), energy-dispersive X-ray analysis (EDX), scanning electron microscopy (SEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), vibrating sample magnetometer (VSM), CHN, zeta potential, and Brunauer-Emmett-Teller (BET) analyses. The adsorption efficiency of the AG-g-PAO/CuFe₂O₄ for removing an organophosphorus pesticide (OPP) (chlorpyrifos) from aqueous solutions was studied. Effect of different experimental conditions such as the pH of the solution, adsorbent dosage, contact time, initial concentration on adsorption efficiency was evaluated. The experimental adsorption data described well by the Langmuir isotherm model and the maximum adsorption capacity (Q_max) of the prepared biosorbent for chlorpyrifos was found 769.23 mg/g. The adsorption kinetic data were well fitted by the pseudo-second-order model. It was suggested that the chlorpyrifos was adsorbed onto AG-g-PAO/CuFe₂O₄ hydrogel biosorbent mainly through electrostatic interaction and hydrogen bonding. The result of adsorption-desorption experiments revealed that the AG-g-PAO/CuFe₂O₄ can be excellently regenerated and reused after three sequential runs without a considerable decline in its adsorption performance.

Keywords: Arabic gum; Chlorpyrifos; Magnetic nanocomposite; Polyamidoxime; Removal.