Simultaneous removal of heavy metals and dyes in water using a MgO-coated Fe3O4 nanocomposite: Role of micro-mixing effect induced by bubble generation

Abstract

This study focused on the development of a nano-adsorbent for contaminant removal without the use of any external energy. An eco-friendly Fe₃O₄@MgO core-shell nanocomposite was synthesized and tested for the removal of a heavy metal, lead (Pb²⁺) and a dye, rhodamine B (RhB). The addition of H₂O₂ into the system enabled the self-mixing of the aqueous solution containing Fe₃O₄@MgO through the generation of bubbles. This system showed an excellent removal efficiency of 99% in just 15 min for Pb²⁺ and 120 min for RhB, which is far better than the control experiment (without H₂O₂). The cation exchange mechanism dominated in the removal of heavy metals, while the adsorptive removal of dye proceeded through the H-bonding between Mg(OH)₂ and dye molecules. The removal efficiency increased exponentially with the increase of H₂O₂ at the optimal concentration of 5% and it was effective over a wide pH range. Moreover, the performance of the Fe₃O₄@MgO-H₂O₂ system was verified for other heavy metals such as Cd, Ni, Zn, Co, and Cu, demonstrating that the Fe₃O₄@MgO-H₂O₂ system can be widely implemented in the treatment of real water matrices contaminated with heavy metals and organic dyes.

Keywords: Adsorption; Bubble generation; Dyes; Fe(3)O(4)@MgO; Heavy metals; Water treatment.