Mechanically robust Janus nanofibrous membrane with asymmetric wettability for high efficiency emulsion separation

Abstract

Water pollution caused by oil leakage or oily sewage has seriously threatened the ecological environment and human health. It remains a tough task for scientists to develop versatile materials to purify different kinds of oily wastewater. In this study, we propose a facile "carbon nanotubes (CNTs) decoration and nanofibrous membrane integration" method to prepare a mechanical robust Janus membrane (JM) composed of a superhydrophilic nanofiber composite layer and a hydrophobic nanofiber composite layer. The asymmetric wettability can be controlled by tuning the thickness of the hydrophobic layer. The nanofiber composite in both two layers possesses a core-shell structure, guaranteeing the excellent flexibility and stretchability of the JM. In addition, the strong interfacial compatibility between the two layers ensures the stability and durability of the JM even after multiple stretching. More importantly, the JM could realize on-demand separation of different kinds of oily wastewater with high separation flux and separation efficiency, including oil/water mixtures with different oil densities, oil-in-water emulsions and water-in-oil emulsions. Furthermore, the JM exhibits cycling stability and long-term serviceability for the emulsion separation. The mechanically robust and stretchable JM has promising applications in purification of various oil contaminated wastewater.

Keywords: Asymmetric wettability; Electrospinning; Emulsion separation; Janus membrane; Oil/water separation.