Bis(η5-cyclo-penta-dien-yl)(2-{[(2-meth-oxy-phen-yl)imino]-meth-yl}phenolato-κ3 O, N, O')terbium

Mikhail E Minyaev; Konstantin A Lyssenko; Dmitrii M Roitershtein; Ilya E Nifant'ev

doi:10.1107/S2056989021013025

Bis(η⁵-cyclo-penta-dien-yl)(2-{[(2-meth-oxy-phen-yl)imino]-meth-yl}phenolato-κ³ O, N, O')terbium

Acta Crystallogr E Crystallogr Commun. 2022 Jan 1;78(Pt 1):44-46. doi: 10.1107/S2056989021013025.

Authors

Mikhail E Minyaev^{1

2}, Konstantin A Lyssenko³, Dmitrii M Roitershtein^{1

2}, Ilya E Nifant'ev^{3

2}

Affiliations

¹ N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospect, Moscow, 119991, Russian Federation.
² A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prospect, Moscow, 119991, Russian Federation.
³ Chemistry Department, M.V. Lomonosov Moscow State University, 1 Leninskie Gory, Str., Building 3, Moscow, 119991, Russian Federation.

Abstract

The air- and moisture-sensitive title compound, [Tb(C₅H₅)₂(C₁₄H₁₂NO₂)], was synthesized from tris-(cyclo-penta-dien-yl)(tetra-hydro-furan)-terbium and 2-{[(2-meth-oxy-phen-yl)imino]-meth-yl}phenol. Each Tb atom is coordinated by two cyclo-penta-dienyl ligands in an η⁵-coordination mode and by one N and two O atoms of the organic ligand in a tridentate κ³ O,N,O'-mode.

Keywords: (methoxyphenyliminomethyl)phenolate; bis(cyclopentadienyl); crystal structure; lanthanide; salicylimino; terbium.

Grants and funding

This work was funded by Russian Science Foundation grant 17-13-01357.