Arsenate removal on the iron oxide ion exchanger modified with Neodymium(III) ions

Abstract

In this study the iron oxide ion exchanger with the quaternary ammonium groups, Ferrix A33E was modified with neodymium (III) ions in order to obtain the new material Ferrix A33E-Nd(III) characterized by greater sorption efficiency of arsenate(V) ions. A33E-Nd(III) was described by various techniques including scanning electron microscopy SEM, nitrogen adsorption/desorption isotherms, Fourier transform infrared spectroscopy FTIR and X-ray photoelectron spectroscopy XPS. The point of zero charge, pH_PZC was also determined. The kinetic and thermodynamic parameters of the arsenate(V) sorption were calculated. The experimental data was fitted to the four isotherm models - Langmuir, Freundlich, Dubinin-Radushkevich and Halsey. Kinetic and equilibrium studies allowed to get to know the behaviour of arsenate(V) ions during the sorption on A33E-Nd(III). The obtained material A33E-Nd(III)- was found to possess a larger maximum sorption capacity than A33E, great stability and the possibility of regeneration at least 3 times without a significant decrease in efficiency. This allows for the complete removal of As(V) ions from a solution with a concentration of 50 mg/dm³ in just 30 min. The Nd(III)-modification improved the sorption properties of the tested ion exchanger.

Keywords: Adsorption; Arsenic; Ferrix A33E; Iron oxides; Neodymium.