Photocatalytic inactivation of algae in a fluidized bed photoreactor with an external magnetic field

Abstract

Practical applications of photocatalysis in algae removal often involve the use of photoreactors, which can be of many different configurations. In this study, a fluidized bed photoreactor (FBPR) with an external magnetic field was designed and constructed to achieve algae inactivation continuously and stably. Magnetic photocatalyst ZnFe₂O₄/Ag₃PO₄/g-C₃N₄ attached to Fe₃O₄ aggregate, was dispersed and fixed at the bottom of the reactor to form a flower-like structure, which can not only increase the effective irradiation area of the photocatalyst, but also enhances mass transfer by inducing flow disturbance. Under the optimal operating conditions, i.e., 0.04 m/s flow rate, 200 mT magnetic field strength, and 0.025 g photocatalyst loading, the photoreactor can effectively remove algae cells within 6 h. During the continuous operation experiment, the quality of the magnetic photocatalyst and aggregate did not decrease significantly, and there was still a 90% removal efficiency after 18 h of continuous operation. Furthermore, in the experiment where humic acid was added to simulate actual water environment, certain advantages can still be observed with the FBPR. As a continuous reactor using a magnetic photocatalyst, the FBPR has the characteristics of high availability, low cost, and low energy consumption.

Keywords: Continuous operation; Fluidized bed photoreactor (FBPR); Magnetic field; Photocatalytic algal inactivation; ZnFe(2)O(4)/Ag(3)PO(4)/g-C(3)N(4).