A novel electrokinetic remediation with in-situ generation of H2O2 for soil PAHs removal

Abstract

Electrokinetic-Fenton (EK-Fenton) technology requires a high dose of H₂O₂ to produce •OH radicals, which adds a high cost to the remediation process and raises safety concerns during transportation and storage of H₂O₂. Moreover, the remediation efficiency of the conventional EK-Fenton process is low due to the meaningless consumption of H₂O₂ on the electrodes and the alkaline environment near the cathode. In this work, a modified CMK3-gas diffusion electrode (CMK3-GDE) is fabricated. This cathode can continuously generate H₂O₂, and the cumulative H₂O₂ concentration can reach 0.23 M during 10 days of the test. The utilization of cation exchange membranes (CEMs) efficiently restricts the decomposition of H₂O₂ on the electrodes and prevents the alkalization of the soil near the cathode, resulting in a 13.7-43.2% increase of the removal efficiency of polycyclic aromatic hydrocarbons (PAHs). In this new treatment process, PAHs are mainly oxidized into quinones, ketones, alcohols, and small molecule acids, and all these products have lower toxicities than PAHs. The EK-Fenton/CMK3-GDE-CEM system exhibits excellent remediation efficiency for treating PAHs polluted soil, which could be a sustainable, eco-friendly, and low-cost strategy for soil remediation.

Keywords: Cation exchange membrane; Electrokinetic-Fenton treatment; Gas diffusion electrode; •OH radicals.