Ecological and human health risks from pseudo-total and bio-accessible metals in street dusts

Abstract

Street dust samples were collected from industrial and commercial cities (Jamshedpur and Ranchi during monsoon and post-monsoon seasons) for detecting the levels of Cr, Cd, Cu, Ni, Pb, Zn, As, Co, Al, and Mn. The industrial city recorded higher metal concentrations compared to commercial. Similar trend of pseudo-total metal concentrations was observed in both the seasons at industrial city (Al > Mn > Zn > Cr > Pb > Cu > Ni > Cd) and only monsoon season at commercial city (Al > Mn > Zn > Cu > Cr > Pb > Ni > Cd). Zn > Cd was the most bioaccessible metal throughout the cities (monsoon and post-monsoon). The geochemical parameters (Igeo, EF, CF) were highest for Cd and lowest for Ni (both cities for the two seasons). Pollution Load Indices (PLI zone) were highest during the post-monsoon season in the industrial city. The highest carcinogenic risk was posed by Cr ranging from 1.87E-05 to 4.80E-05, in both the cities through ingestion and inhalation pathways. Children were found at higher risks, while the bioaccessible fractions posed neither carcinogenic nor non-carcinogenic threats to the population. Principal component analysis and correlation analysis indicated the influence of vehicular and industrial emissions, especially steel industry and coal-based thermal power plants as the major source of metals in street-dust. The outcomes of this work will be useful in providing baseline information of pollution along with their consequent environmental and human health risks of Jharkhand state.

Keywords: Carcinogenic risks; Ecological risks; Geoaccumulation index; Hazard quotient; Non-carcinogenic risks; Pollution Load Index.