Enhanced carriers separation in novel in-plane amorphous carbon/g-C3N4 nanosheets for photocatalytic environment remediation

Abstract

Although carbon-based materials/g-C₃N₄ heterostructure with an up-down structure in space can inhibit the recombination of charge carriers, the electron transfer is still suppressed by the interlayer van der Waals force. Herein, amorphous carbon is successfully introduced into the g-C₃N₄ nanosheet (CNS) by a self-conversion process to form an in-plane heterostructure of amorphous carbon/g-C₃N₄ (CNSC₁). Kelvin probe atomic force microscopy (KPFM) and density functional theory (DFT) confirm that g-C₃N₄ and amorphous carbon are in the same plane, which can generate the surface electric field of CNSC₁, providing a driving force for the transfer of electrons from g-C₃N₄ to amorphous carbon. Meanwhile, the sp²-hybridized π conjugation bond of amorphous carbon can rapidly capture and store photogenerated electrons, inhibiting charge carrier recombination and thus generating more electrons to facilitate the yield of hydroxyl radicals. The photocatalytic activity of CNSC₁ for the degradation of tetracycline and rhodamine B is 2.7 times and 4.8 times higher than that of CNS, respectively, due to the efficient interface charge separation. This work is expected to provide a new idea for the combination of carbon materials and g-C₃N₄.

Keywords: Amorphous carbon; G-C(3)N(4) nanosheets; In-plane structure; Photocatalytic degradation; Surface electric field.