Efficient adsorptive removal of fluoroquinolone antibiotics from water by alkali and bimetallic salts co-hydrothermally modified sludge biochar

Abstract

Fluoroquinolones are one of most commonly used antibiotics for preventing and treating bacterial infections and their unsatisfactory removal by conventional wastewater treatment technology have aroused widespread attention. A novel adsorbent of KMSBC was the first time synthesized and tested to adsorb three typical fluoroquinolone antibiotics of CIP, NOR and OFL from water. The characterization analysis showed that KMSBC possessed the superior porous structure, abundant functional groups and greater graphitic degree. Together with kinetics, isotherms, thermodynamics and critical factors (e.g., biochar dose, reaction time/temperature, fluoroquinolone antibiotics concentration, pH, co-existing ionic strength and HA concentration) analysis suggested that pore filling, π-π conjugation, H-bonding and electrostatic interaction were the key mechanisms for fluoroquinolone antibiotics adsorption by KMSBC. KMSBC exhibited the optimum adsorption performance at pH = 5 despite the adsorbates. The maximum adsorption capacity of KMSBC for CIP, NOR and OFL were 49.9, 55.7 and 47.4 mg/g at 25 °C, respectively. Also, KMSBC exhibited the good magnetic sensitivity and stability with the leaching concentrations of Fe were far below than environmental limit (GB5749-2006) at various pH (from 3 to 12), ionic strength and HA concentrations. Additionally, KMSBC performed a stable sustainable adsorption performance in recycles by NaOH regeneration. Thus, KMSBC had the potential to be a promising adsorbent for fluoroquinolone antibiotics removal with favorable adsorption capacity, environmental security and easy regeneration performance.

Keywords: Bimetallic salts; Fluoroquinolones; Hydrothermal activation; Potassium hydroxide; Sludge biochar.