Carbon Materials as Positive Electrodes in Bromine-Based Flow Batteries

Abstract

Bromine based redox flow batteries (RFBs) can provide sustainable energy storage due to the abundance of bromine. Such devices pair Br₂ /Br^- at the positive electrode with complementary redox couples at the negative electrode. Due to the highly corrosive nature of bromine, electrode materials need to be corrosion resistant and durable. The positive electrode requires good electrochemical activity and reversibility for the Br₂ /Br^- couple. Carbon materials enjoy the advantages of low cost, excellent electrical conductivity, chemical resistance, wide operational potential ranges, modifiable surface properties, and high surface area. Here carbon based materials for bromine electrodes are reviewed, with a focus on application in zinc-bromine, hydrogen-bromine, and polysulphide-bromine RFB systems, aiming to provide an overview of carbon materials to be used for design and development of bromine electrodes with improved performance. Aspects deserving further R&D are highlighted.

Keywords: bromine electrode; carbon materials; hydrogen bromine; polysulfide bromine; zinc bromine redox flow battery.