The exacerbating water pollution and water resource shortage pose a great danger to human health and make it imperative to recycle and treat the sewage. In this study, a direct-writing three-dimensional (3D) printing technology was adopted to prepare a 3D sodium alginate (SA)/graphene oxide (GO)/Ag nanoparticle (AgNP) aerogel (SGA), aiming to turn the complex sewage containing oil, silt, and bacteria into clean water depending only on gravity separation. The physicochemical properties and surface structure of the synthesized SGA were characterized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The swelling rate, mechanical properties, antibacterial properties, oil and water separation effect, and durable stability of the filter membrane were also investigated to verify the versatility of the SGA filter. The results showed that GO helped improve the mechanical properties of the printed filter to withstand water impact during the filtration process. The printed filter had a well-designed and multiscale gradient pore structure, which can effectively intercept particles with different sizes to separate the silt from water, and the turbidity of the filtered water can be reduced from 60 to 1 nephelometric turbidity unit (NTU). The presence of SA endowed the printed filter with hydrophilic and oleophobic behaviors, which can effectively separate various kinds of oils from water. The uniform distribution of AgNPs in the filter produced via a facile and green reduction of SA facilitated the efficient bactericidal ability of the printed filter during the filtration process; meanwhile, the lower release concentration of Ag ions ensured drinking safety. What is more, the filter can be easily produced on a large scale and used for different sewage treatment situations with a durable stability of over 30 days. Taken together, the printed SGA filter has a broad application prospect in complex sewage treatment, providing a special solution for sewage treatment in poverty areas.
Keywords: 3D printing; Ag nanoparticles; antibacterial; graphene oxide; oil−water separation; sewage treatment.