A covalent organic framework as a photocatalyst for window ledge cross-dehydrogenative coupling reactions

Fan Yang; Cong-Cong Li; Cui-Cui Xu; Jing-Lan Kan; Bing Tian; Hong-Yan Qu; Yuan Guo; Yan Geng; Yu-Bin Dong

doi:10.1039/d1cc06184d

A covalent organic framework as a photocatalyst for window ledge cross-dehydrogenative coupling reactions

Chem Commun (Camb). 2022 Feb 1;58(10):1530-1533. doi: 10.1039/d1cc06184d.

Authors

Fan Yang¹, Cong-Cong Li¹, Cui-Cui Xu¹, Jing-Lan Kan¹, Bing Tian¹, Hong-Yan Qu¹, Yuan Guo², Yan Geng¹, Yu-Bin Dong¹

Affiliations

¹ College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, P. R. China. gengyan@sdnu.edu.cn.
² School of Light Industry and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China.

PMID: 35005752
DOI: 10.1039/d1cc06184d

Abstract

A benzothiadiazole-involving donor-acceptor (D-A) covalent organic framework (COF), which has high crystallinity and strong light-harvesting capability (ranging from 300 to 800 nm), can serve as a highly effective photocatalyst for window ledge aerobic cross-dehydrogenative coupling (CDC) reactions (such as Mannich and aza-Henry reactions) even at a gram level.