Stronger-together: the cooperativity of aurophilic interactions

Chem Commun (Camb). 2022 Jan 27;58(9):1398-1401. doi: 10.1039/d1cc05241a.

Abstract

Crystallographic distances and the electron density of bi- and tri-nuclear gold(I) compounds reveal that the existence of multiple Au⋯Au interactions increases their individual strength in the order of 0.9-2.9 kcal mol-1. We observed this behaviour both experimentally and theoretically in multinuclear systems, confirming a novel important cooperative character in aurophilic contacts.