Bi-functional super-hydrophilic/underwater super-oleophobic 2D lamellar Ti3C2Tx MXene/poly (arylene ether nitrile) fibrous composite membrane for the fast purification of emulsified oil and photodegradation of hazardous organics

Abstract

Developing the multi-functional membranes including oil/water emulsion separation and removal of hazardous organic pollutants is essential to the purification of the complicated wastewater. However, it remains a daunting challenge to combine these intended functions while maintaining high separation efficiency. Herein, we developed a new 2D lamellar MXene/poly (arylene ether nitrile) (PEN) fibrous composite membrane through the self-assembly of TiO₂ nanoparticles intercalated MXene nanosheets onto the porous PEN nanofibrous mats and bioinspired polydopamine triggered chemical-crosslinking with polyethyleneimine (PEI). Such nano-intercalation and mussel-inspired crosslinking could effectively regulate the interlayer spacing of the MXene nanosheet skin layer and surface wettability of the composite membrane, which also further contributed to the fast separation and unique bifunctional feature. It was found that the MXene@TiO₂/PEN fibrous composite membrane exhibited low oil-adhesion and superhydrophilic (WCA = 0°)/underwater superoleophobic (UOCA > 155°) properties, which could efficiently separate various surfactant-stabilized oil-in-water emulsions under low pressure of 0.04 MPa while keeping good stability (Under 1 M HCl and 2 M NaOH solutions) and recyclability. Interestingly, the fibrous composite membrane achieved favorable permeation flux of 908-1003 Lm^-2h^-1 (2270-2507.5 Lm^-2h^-1bar^-1) in comparison to other reported MXene based multifunctional composite membranes. Moreover, owing to the synergistic effect of MXene nanosheets and TiO₂ nanoparticles, the MXene@TiO₂/PEN membrane showed excellent photocatalytic degradation performance for various dyes under visible light, i.e. the photocatalytic degradation efficiency for 15 ppm MB, MO, CV, and MeB solutions achieved 92.31%, 93.50%, 98.06%, and 99.30% within 60 min, respectively. Such 2D MXene bio-functional composite membranes with outstanding oil/water emulsions separation and photocatalytic degradation of dyes pave an avenue for treating complicated oily wastewater.

Keywords: Composite membrane; Dyes; MXene nanosheets; Oil/water separation; Photocatalytic degradation.