Triple-stranded triptycene-based metallo-supramolecular helicate displaying efficient encapsulation of bulky guest molecules

Chem Commun (Camb). 2022 Jan 27;58(9):1326-1329. doi: 10.1039/d1cc05974b.

Abstract

Triple-stranded metallo-supramolecular helicates were readily constructed by achieving a coordination of the gallium(iii) cation by ligands based on 2,7- and 2,6-disubstituted triptycenes. The significance of these building blocks in the construction of helicates with the capability for guest encapsulation was also revealed.