Microwave-assisted green synthesis of multi-functional carbon quantum dots as efficient fluorescence sensor for ultra-trace level monitoring of ammonia in environmental water

Abstract

This study reports a facile green preparation of self-assembled multi-functional carbon quantum dots (CQDs) via direct pyrolysis technique coupled with microwave-assisted synthesis using Ziziphus Mauritiana stone biomass (as a bio-resource precursor). The synthesized multi-functional CQDs was characterized using FT-IR, XRD, XPS, TEM, and fluorescence spectroscopy techniques. The results exhibit that the prepared CQDs are spherical-shaped with an average diameter of 2-4 nm and showed bright bluish-green emissions property with stable dispersion and high photostability in the aqueous medium. Furthermore, the emission properties of CQDs were examined by quenched with ammonia (NH₃) and other molecules in aqueous media. Results indicated that the developed CQDs showed effective fluorescent for the selective and sensitive detection (sensor) of NH₃ with a detection limit of 10 nM. Thus, the presented procedure is a simple, low-cost, efficient, chemical-free synthesis of CQDs and can be applied as selective and sensitive (sensor) monitoring of NH₃ concentration in aquatic environmental samples.

Keywords: Ammonia detection; Carbon quantum dots; Environmental water; Fluorescence; Microwave-assisted synthesis; Ziziphus mauritiana biomass.