Shape Engineering of TiO2 Microrobots for "On-the-Fly" Optical Brake

Small. 2022 Mar;18(10):e2106271. doi: 10.1002/smll.202106271. Epub 2021 Dec 18.

Abstract

Hybrid microrobots have recently attracted attention due to their ability to combine different energy sources and/or external stimuli for propulsion and performing desired tasks. Despite progresses in the past, on-demand speed modulation for hybrid microrobots has not been analyzed in detail. Herein, the influence of surface properties and crystallite size on the propulsion mechanism of Pt/TiO2 chemical/light-driven hybrid microrobots is investigated. The morphology of urchin-like Pt/TiO2 microrobots leads to "on-the-fly" optical brake behavior under UV irradiation. In contrast, smooth Pt/TiO2 microrobots demonstrate accelerated motion in the same conditions. The comparison between two types of microrobots also indicates the significance of a high surface area and a high crystallite size to increase their speed. The results demonstrate the profound impact of surface features for next-generation smart micro/nanorobots with on-demand reaction capability in dynamically changing environments.

Keywords: UV light; chemical propulsion; electrophoresis; janus microrobots; micromotors; self-propelled microrobots.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Titanium*

Substances

  • titanium dioxide
  • Titanium