In the present study, the oxidative desulfurization (ODS) of Sn 650 base oil with total sulfur content of 10,000 ppmw has been investigated experimentally. The response surface methodology (RSM) considering Box-Behnken design (BBD) was applied to examine the impacts of the oxidation temperature (30-70˚C), hydrogen peroxide to sulfur molar ratio (2-8), and formic acid to sulfur molar ratio (20-60) on the sulfur removal. In the next step, the appropriate values of the independent variables such as stirrer speed (750-1250 rpm), reaction time (60-180 min), and the number of extraction stages (1-4) were determined based on the optimal result obtained from the BBD. The best performance of the ODS process was found at a reaction temperature of 58˚C, an oxidant to sulfur molar ratio of 7.35, a formic acid to sulfur molar ratio of 58.5, a reaction time of 150 min, and a stirrer speed of 1250 rpm for the oxidation reaction. The achieved sulfur removal after oxidation followed by liquid-liquid extraction was 32 %, and 60 % for one extraction and three extraction stages, respectively. The changes in the base oil specifications after the ODS treatment were also investigated.
Keywords: Extraction; Lubricant base oil; Oxidative desulfurization; Response surface methodology (RSM); Sulfur removal.
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