Gas chromatography of essential oil: State-of-the-art, recent advances, and perspectives

J Sep Sci. 2022 Jan;45(1):94-112. doi: 10.1002/jssc.202100681.

Abstract

This review is an overview of the recent advances of gas chromatography in essential oil analysis; in particular, it focuses on both the new stationary phases and the advanced analytical methods and instrumentations. A paragraph is dedicated to ionic liquids as gas chromatography stationary phases, showing that, thanks to their peculiar selectivity, they can offer a complementary contribution to conventional stationary phases for the analysis of complex essential oils and the separation of critical pairs of components. Strategies to speed-up the analysis time, thus answering to the ever increasing request for routine essential oils quality control, are also discussed. Last but not least, a paragraph is dedicated to recent developments in column miniaturization in particular that based on microelectromechanical-system technology in a perspective of developing micro-gas chromatographic systems to optimize the energy consumption as well as the instrumentation dimensions. A number of applications in the essential oil field is also included.

Keywords: conventional gas chromatography; enantioselective analysis; essential oils; fast gas chromatography; miniaturized gas chromatography.

Publication types

  • Review

MeSH terms

  • Chromatography, Gas / instrumentation
  • Chromatography, Gas / methods*
  • Chromatography, Gas / trends
  • Ionic Liquids / chemistry
  • Molecular Structure
  • Oils, Volatile / chemistry*
  • Plant Oils / chemistry*

Substances

  • Ionic Liquids
  • Oils, Volatile
  • Plant Oils