Synergistic solidification/stabilization of electrolytic manganese residue and carbide slag

Abstract

Electrolytic manganese residue (EMR) contains high concentrations of NH₄⁺ and heavy metals, such as Mn²⁺, Zn²⁺, Cu²⁺, Pb²⁺, Ni²⁺ and Co²⁺, while carbide slag (CS) contains high amount of OH^- and CO₃^2-, both posing a serious threat to the ecosystem. In this study, EMR and CS synergistic stabilization/solidification (S/S) was discussed science CS could stabilize or solidify EMR and simultaneously reduce its corrosive. The results showed that after the synergistic S/S for 24 h when liquid-solid ratio was 17.5% and CS dosage was 7%, Mn²⁺ and NH₄⁺ leaching concentrations of the S/S EMR were below the detection limits (0.02 mg/L and 0.10 mg/L) with a pH value of 8.8, meeting the requirements of the Chinese integrated wastewater discharge standard (GB 8978-1996). Mn²⁺ was stabilized as MnFe₂O₄, Mn₂SiO₄, CaMnSi₂O₆, and NH₄⁺ escaped as NH₃. Zn²⁺, Cu²⁺, Pb²⁺, Ni²⁺ and Co²⁺ in EMR can also be stabilized/solidified because of the react with OH^- and CO₃^2- in CS. Chemical cost was only $ 0.54 for per ton of EMR synergistic harmless treatment with CS. This study provided a new idea for EMR cost-effective and environment-friendly harmless treatment.

Keywords: Carbide slag; Chemical speciation; Electrolytic manganese residue; Harmless treatment; Manganese and ammonia nitrogen.