Borole-based half-sandwich complexes of germanium and tin

Chem Commun (Camb). 2021 Dec 23;58(2):246-249. doi: 10.1039/d1cc06227a.

Abstract

The synthesis and initial observations regarding the reactivity of borole-based half-sandwich complexes with apical divalent group 14 elements germanium and tin are described. The 2,5-disilylborole substitution pattern allows their access via salt metathesis of the respective borole dianions.