Co-Existence of Iron Oxide Nanoparticles and Manganese Oxide Nanorods as Decoration of Hollow Carbon Spheres for Boosting Electrochemical Performance of Li-Ion Battery

Karolina Wenelska; Martyna Trukawka; Wojciech Kukulka; Xuecheng Chen; Ewa Mijowska

doi:10.3390/ma14226902

Co-Existence of Iron Oxide Nanoparticles and Manganese Oxide Nanorods as Decoration of Hollow Carbon Spheres for Boosting Electrochemical Performance of Li-Ion Battery

Materials (Basel). 2021 Nov 15;14(22):6902. doi: 10.3390/ma14226902.

Authors

Karolina Wenelska¹, Martyna Trukawka¹, Wojciech Kukulka¹, Xuecheng Chen¹, Ewa Mijowska¹

Affiliation

¹ Department of Nanomaterials Physicochemistry, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology, Szczecin, Piastow Ave. 42, 71-065 Szczecin, Poland.

Abstract

Here, we report that mesoporous hollow carbon spheres (HCS) can be simultaneously functionalized: (i) endohedrally by iron oxide nanoparticle and (ii) egzohedrally by manganese oxide nanorods (Fe_xO_y/MnO₂/HCS). Detailed analysis reveals a high degree of graphitization of HCS structures. The mesoporous nature of carbon is further confirmed by N₂ sorption/desorption and transmission electron microscopy (TEM) studies. The fabricated molecular heterostructure was tested as the anode material of a lithium-ion battery (LIB). For both metal oxides under study, their mixture stored in HCS yielded a significant increase in electrochemical performance. Its electrochemical response was compared to the HCS decorated with a single component of the respective metal oxide applied as a LIB electrode. The discharge capacity of Fe_xO_y/MnO₂/HCS is 1091 mAhg^-1 at 5 Ag^-1, and the corresponding coulombic efficiency (CE) is as high as 98%. Therefore, the addition of MnO₂ in the form of nanorods allows for boosting the nanocomposite electrochemical performance with respect to the spherical nanoparticles due to better reversible capacity and cycling performance. Thus, the structure has great potential application in the LIB field.

Keywords: battery; carbon spheres; metal oxide nanoparticles.