Crevice corrosion has become an important issue of the safety of AISI 304L austenitic stainless steel canister when exposed to the chloride environments located in coastal areas. Moreover, dust deposited on the canister surface may enhance the corrosion effect of 304L stainless steel. In this work, white emery was adopted to simulate the dust accumulated on the as-machined specimen surface. To investigate the effect of deposited white emery, chloride concentration, and relative humidity on the crevice corrosion behavior, an experiment was conducted on 304L stainless steel specimens at 45 °C with 45%, 55%, and 70% relative humidity (RH) for 7000 h. The surface features and crack morphology of the tested 304L stainless steel specimens were examined by SEM equipped with energy-dispersive spectrometry (EDS) and electron back scatter diffraction (EBSD). From the experimental results, a threshold RH for the stress corrosion cracking (SCC) initiation of AISI 304L austenitic stainless steel with different concentrations of chloride was proposed.
Keywords: chloride concentration; crevice corrosion; dust; relative humidity; stainless steel; stress corrosion cracking.