Topology and Phase Transitions: A First Analytical Step towards the Definition of Sufficient Conditions

Entropy (Basel). 2021 Oct 27;23(11):1414. doi: 10.3390/e23111414.

Abstract

Different arguments led to supposing that the deep origin of phase transitions has to be identified with suitable topological changes of potential related submanifolds of configuration space of a physical system. An important step forward for this approach was achieved with two theorems stating that, for a wide class of physical systems, phase transitions should necessarily stem from topological changes of energy level submanifolds of the phase space. However, the sufficiency conditions are still a wide open question. In this study, a first important step forward was performed in this direction; in fact, a differential equation was worked out which describes how entropy varies as a function of total energy, and this variation is driven by the total energy dependence of a topology-related quantity of the relevant submanifolds of the phase space. Hence, general conditions can be in principle defined for topology-driven loss of differentiability of the entropy.

Keywords: Ginzburg-Landau; Weingarten map; differential topology; entropy flow; phase transitions.