Outstanding performance of sulfurated titanomaghemite (Fe2TiO5) for hexavalent chromium removal: Sulfuration promotion mechanism and its application in chromium resource recovery

Abstract

A lot of magnetic sorbents have been developed to meet the current demand for removing Cr (VI) from wastewater. However, the application of magnetic sorbents remains restricted by the unsatisfactory Cr (VI) removal efficiency, sorbent regeneration, and safe disposition of adsorbed Cr species. In this study, magnetic titanomaghemite (Fe₂TiO₅) was sulfurated with gaseous H₂S to improve its Cr (VI) removal efficiency. Sulfuration significantly improved the Cr (VI) removal efficiency of Fe₂TiO₅ from 3%-14% to 27%-82% at pH 4-10 due to drastically increased the electrostatic adsorption of Cr (VI) and heterogeneous reduction of adsorbed Cr (VI) to Cr (III). Furthermore, the sulfurated Fe₂TiO₅ recovered using magnetic separation can be regenerated by re-sulfuration without degrading the Cr (VI) removal efficiency, therefore, sulfurated Fe₂TiO₅ can be recycled for Cr (VI) removal after the regeneration. Moreover, Cr (VI) in aqueous solution can be enriched on sulfurated Fe₂TiO₅ after multiple adsorptions in the form of Cr₂O₃ in a content of more than 30% what can be considered as a source of chrome ore. Therefore, sulfurated Fe₂TiO₅ may be a promising, low-cost, and environment-friendly sorbent for Cr recovery as a co-benefit of Cr (VI) removal from wastewater.

Keywords: Cr (VI) removal; Cr resource recovery; Kinetic analysis; Magnetic sulfurated Fe(2)TiO(5); Sorbent regeneration.