Effect of sulfide on morphology and particle size of biologically produced elemental sulfur from industrial desulfurization reactors

Abstract

We investigated the effect of polysulfide formation on properties of biologically produced elemental sulfur (S₈) crystals, which are produced during biological desulfurization (BD) of gas. The recent addition of an anoxic-sulfidic reactor (AnSuR) to the BD process resulted in agglomerated particles with better settleability for S₈ separation. In the AnSuR, polysulfides are formed by the reaction of bisulfide (HS^-) with S₈ and are subsequently oxidized to S₈ in a gas-lift reactor. Therefore, sulfur particles from the BD are shaped (i.e. morphology and particle size) both by formation and dissolution. We assessed the reaction of HS^- with S₈ particles in anoxic, abiotic experiments in a batch reactor using two S₈ samples from industrial BD reactors. Under these conditions, the sulfur particle surface became coarser and more porous, and in addition the smallest particles disappeared. Agglomerates initially fell apart but were reformed at a later stage. Moreover, we found different observed polysulfide formation rates for each S₈ sample, which was related to the initial morphology and size. Our findings show that particle properties can be controlled abiotically and that settleability of S₈ is increased by increasing both the HS^--S₈ ratio and retention time.

Keywords: biodesulfurization; hydrogen sulfide; particle size analysis; polysulfide; settleability.